Catalytic cracking of oil
Catalysts used in the cracking of crude oil are usually hydrated aluminum silicates. Zeolites, or molecular sieves, are hydrated aluminosilicates having a very porous crystalline structure, in which water molecules are trapped. The formation of branched-chain alkanes, or iso-alkanes, leads to the production of gasoline with high octane numbers. This is the fundamental reason why catalytic cracking has replaced thermal cracking as the central process in a refinery geared to maximize gasoline production. Carbon is deposited on the catalyst during the cracking process. This carbon, known as catalyst coke, adheres to the catalyst, reducing its ability to crack the oil. The coke on the spent catalyst is burned off, which reheats the catalyst to add heat to the FCC process. fluid catalytic cracking - a hot, fluid catalyst (1000 degrees Fahrenheit / 538 degrees Celsius) cracks heavy gas oil into diesel oils and gasoline. hydrocracking - similar to fluid catalytic cracking, but uses a different catalyst, lower temperatures, higher pressure, and hydrogen gas. It takes heavy oil and cracks it into gasoline and kerosene (jet fuel). Fluid catalytic cracking is a commonly used process, and a modern oil refinery will typically include a cat cracker, particularly at refineries in the US, due to the high demand for gasoline. The process was first used around 1942 and employs a powdered catalyst. During WWII, the Allied Forces had plentiful supplies of the materials in contrast to the Axis Forces, which suffered severe shortages of gasoline and artificial rubber. Catalytic Cracking. A catalyst allows lower reaction temperatures to be used. In fluidised catalytic cracking, the feedstock is gas oil which is vaporised and passed through a zeolite, produced as a fine powder (Unit 2), heated to about 700-800 K in the reactor. Fluid catalytic cracking (FCC) is a refining process of gas oil, which could not be distilled in an atmospheric tower, into lighter transportation fuel by reducing the molecules of the heavy oil by use of a catalyst, pressure and heat.
Cyclic fixed bed catalytic cracking commercialized in late 1930s. 1stHoudryProcess Corporation catalyst cracker started up at Sun Oil’s Paulsboro, New Jersey, refinery in June 1936 Three fixed bed reactors & processed 2,000 barrels/day Other adoptees: Sun, Gulf, Sinclair, Standard Oil of Ohio, & The Texas Company.
Two of the most intensive and commonly used catalytic cracking processes in crude oil refining are fluid catalytic cracking and hydrocracking. In the fluid catalytic cracking process, the fine, powdery catalyst (typically zeolites, which have an average particle size of ~ 70 μm) takes on the properties of a fluid when it is mixed with the vaporized feed. Main Difference – Thermal Cracking vs Catalytic Cracking. Petroleum refining is the processing of crude oil in order to obtain desired products. There are several petroleum refining processes that are helpful in converting crude oil into useful products. A refinery is a large industrial area that is composed of a number of processing units. Catalysts used in the cracking of crude oil are usually hydrated aluminum silicates. Zeolites, or molecular sieves, are hydrated aluminosilicates having a very porous crystalline structure, in which water molecules are trapped. The formation of branched-chain alkanes, or iso-alkanes, leads to the production of gasoline with high octane numbers. This is the fundamental reason why catalytic cracking has replaced thermal cracking as the central process in a refinery geared to maximize gasoline production. Carbon is deposited on the catalyst during the cracking process. This carbon, known as catalyst coke, adheres to the catalyst, reducing its ability to crack the oil. The coke on the spent catalyst is burned off, which reheats the catalyst to add heat to the FCC process. fluid catalytic cracking - a hot, fluid catalyst (1000 degrees Fahrenheit / 538 degrees Celsius) cracks heavy gas oil into diesel oils and gasoline. hydrocracking - similar to fluid catalytic cracking, but uses a different catalyst, lower temperatures, higher pressure, and hydrogen gas. It takes heavy oil and cracks it into gasoline and kerosene (jet fuel). Fluid catalytic cracking is a commonly used process, and a modern oil refinery will typically include a cat cracker, particularly at refineries in the US, due to the high demand for gasoline. The process was first used around 1942 and employs a powdered catalyst. During WWII, the Allied Forces had plentiful supplies of the materials in contrast to the Axis Forces, which suffered severe shortages of gasoline and artificial rubber.
Carbon is deposited on the catalyst during the cracking process. This carbon, known as catalyst coke, adheres to the catalyst, reducing its ability to crack the oil. The coke on the spent catalyst is burned off, which reheats the catalyst to add heat to the FCC process.
fluid catalytic cracking - a hot, fluid catalyst (1000 degrees Fahrenheit / 538 degrees Celsius) cracks heavy gas oil into diesel oils and gasoline. hydrocracking - similar to fluid catalytic cracking, but uses a different catalyst, lower temperatures, higher pressure, and hydrogen gas. It takes heavy oil and cracks it into gasoline and kerosene (jet fuel). Fluid catalytic cracking is a commonly used process, and a modern oil refinery will typically include a cat cracker, particularly at refineries in the US, due to the high demand for gasoline. The process was first used around 1942 and employs a powdered catalyst. During WWII, the Allied Forces had plentiful supplies of the materials in contrast to the Axis Forces, which suffered severe shortages of gasoline and artificial rubber.
Crude oil is a finite resource. Petrol and other fuels are produced from it using fractional distillation. Cracking is used to convert long alkanes into shorter, more useful hydrocarbons.
fluid catalytic cracking - a hot, fluid catalyst (1000 degrees Fahrenheit / 538 degrees Celsius) cracks heavy gas oil into diesel oils and gasoline. hydrocracking - similar to fluid catalytic cracking, but uses a different catalyst, lower temperatures, higher pressure, and hydrogen gas. It takes heavy oil and cracks it into gasoline and kerosene (jet fuel). Fluid Catalytic Cracking Unit (FCC): FCC is one of the most important conversions processes used in oil refinery process. The purpose of FCC unit is to transfer heavy crude oil into light oil. Under the action of heat and catalyst, upgrades the heavier, higher-boiling fractions from the crude oil distillation by Cyclic fixed bed catalytic cracking commercialized in late 1930s. 1stHoudryProcess Corporation catalyst cracker started up at Sun Oil’s Paulsboro, New Jersey, refinery in June 1936 Three fixed bed reactors & processed 2,000 barrels/day Other adoptees: Sun, Gulf, Sinclair, Standard Oil of Ohio, & The Texas Company. The process is known as Catalytic Cracking because it only happens in the presence of a catalyst (substance which speeds up the reaction without being used up itself). In College you will have used Main Difference – Catalytic Cracking vs Catalytic Reforming. Catalytic cracking and catalytic reforming are two processes used in the conversion of crude oil into useful products. Catalytic cracking is the breakdown of large hydrocarbon compounds into small hydrocarbon molecules with the use of moderate temperatures and pressures in the presence of catalysts. Catalytic cracking is a heterogeneously acid-catalyzed reaction. In order for catalytic cracking reactions to take place, the reactants should be able to reach the active sites on the surface of the catalysts. There are several steps involved in the introduction of reactant and its final formation as product(s).
Main Difference – Thermal Cracking vs Catalytic Cracking. Petroleum refining is the processing of crude oil in order to obtain desired products. There are several petroleum refining processes that are helpful in converting crude oil into useful products. A refinery is a large industrial area that is composed of a number of processing units.
Main Difference – Catalytic Cracking vs Catalytic Reforming. Catalytic cracking and catalytic reforming are two processes used in the conversion of crude oil into useful products. Catalytic cracking is the breakdown of large hydrocarbon compounds into small hydrocarbon molecules with the use of moderate temperatures and pressures in the presence of catalysts. Catalytic cracking is a heterogeneously acid-catalyzed reaction. In order for catalytic cracking reactions to take place, the reactants should be able to reach the active sites on the surface of the catalysts. There are several steps involved in the introduction of reactant and its final formation as product(s).
Carbon is deposited on the catalyst during the cracking process. This carbon, known as catalyst coke, adheres to the catalyst, reducing its ability to crack the oil. The coke on the spent catalyst is burned off, which reheats the catalyst to add heat to the FCC process. fluid catalytic cracking - a hot, fluid catalyst (1000 degrees Fahrenheit / 538 degrees Celsius) cracks heavy gas oil into diesel oils and gasoline. hydrocracking - similar to fluid catalytic cracking, but uses a different catalyst, lower temperatures, higher pressure, and hydrogen gas. It takes heavy oil and cracks it into gasoline and kerosene (jet fuel).